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Only idiots would buy silicone alone on stopper, what's used is always silicone coated with PTFE so there is no incompatibility there as the PTFE is well compatible with BB.Maybe for low BB brews silicone is prefered over rubber. Or maybe the incompatibility of butyl rubber with MCT(and most oils) in any case outweigh the incompatibility of silicone with BB.
Would be interesting to know how incompatible silicone is with BB.