So not only is it possible to create AA and NA but AA are found on EXTRATERRESTRIAL objects in the universe meaning their formation is likely relatively common. It is quite possible this planet was seeded by these extraterrestrial objects. Interested to know how creationism deals with extraterritorial sources of organic molecules?
Adv Space Res. 1984;4(12):125-31.
Prebiotic syntheses of purines and pyrimidines.
Basile B, Lazcano A, Oró J.
Collaborators (1)
Source
Department of Biochemical and Biophysical Sciences, University of Houston, TX 77004, USA.
Abstract
The work done in many laboratories during the last two decades has confirmed that hydrogen cyanide and cyanoacetylene are the two major precursors for the prebiotic synthesis of purines and pyrimidines, respectively. Although several different pathways for the synthesis of purines have been described, they are all variations of the initial mechanism proposed by Oró and Kimball, where hydrogen cyanide leads first to the formation of a 4,5-di-substituted imidazole derivative, and then to the closing of the purine ring with a C1 compound. A number of experiments have shown that purines and pyrimidines can also be obtained from methane, ammonia (nitrogen), and water mixtures, provided an activating source of energy (radiation, electric discharges, etc.) is available. However, in this case the yields are lower by about two orders of magnitude because of the intermediate formation of hydrogen cyanide and cyanoacetylene. The latter two compounds have been found in interstellar space, Titan and other bodies of the solar system. They were probably present in the primordial parent bodies from the solar nebula in concentrations of 10(-2) to 10(-3) M as inferred from recent calculations by Miller and coworkers obtained for the Murchison meteorite. These concentrations should have been sufficient to generate relatively large amounts of purine and pyrimidine bases on the primitive Earth.
Chem Scr. 1986;26B:5-11.
Current status of the prebiotic synthesis of small molecules.
Miller SL.
Collaborators (1)
Source
Department of Chemistry, University of California, San Diego, La Jolla 92093, USA.
Abstract
The prebiotic synthesis of small molecules has been accomplished using various simulated atmospheres with CH4, N2, and NH3, H2O being the most effective, but H2, CO, N2, H2O and H2, CO2, N2, H2O also give good yields of organic compounds provided H2/CO > 1 and H2/CO2 > 2. The spark discharge is a very effective source of energy in such experiments, because it is a good source of HCN. Ultraviolet light would also have been important on the primitive earth. Almost all prebiotic amino acids are made by the hydrolysis of an amino nitrile formed from an aldehyde, NH3 and HCN (Strecker synthesis). There are reasonable prebiotic syntheses worked out for the twenty amino acids that occur in proteins, with the exception of lysine, arginine and histidine. The purines are derived from the polymerization of HCN, and the precursor of the pyrimidines is cyanoacetylene. The sugars (including ribose), would have been formed from the base catalyzed polymerization of formaldehyde. There is no good prebiotic synthesis of straight chain fatty acids. Of the vitamin coenzymes, only nicotinic acid has been synthesized under prebiotic conditions. Many of the molecules that are produced in these simulated primitive earth experiments are found in a group of meteorites that contain organic compounds, called the carbonaceous chondrites. Since such prebiotic syntheses took place on the parent body of the carbonaceous chondrites, generally thought to be an asteroid, it is plausible, but not proved, that such syntheses took place on the primitive earth, and that the first living organisms were formed out of these compounds.
Chem Soc Rev. 2012 Aug 21;41(16):5459-72. doi: 10.1039/c2cs35109a. Epub 2012 Jun 15.
Understanding prebiotic chemistry through the analysis of extraterrestrial amino acids and nucleobases in meteorites.
Burton AS, Stern JC, Elsila JE, Glavin DP, Dworkin JP.
Source
Oak Ridge Associated Universities, Greenbelt, MD 20771, USA.
Abstract
The discoveries of amino acids of extraterrestrial origin in many meteorites over the last 50 years have revolutionized the Astrobiology field. A variety of non-terrestrial amino acids similar to those found in life on Earth have been detected in meteorites. A few amino acids have even been found with chiral excesses, suggesting that meteorites could have contributed to the origin of homochirality in life on Earth. In addition to amino acids, which have been productively studied for years, sugar-like molecules, activated phosphates, and nucleobases have also been determined to be indigenous to numerous meteorites. Because these molecules are essential for life as we know it, and meteorites have been delivering them to the Earth since accretion, it is plausible that the origin(s) of life on Earth were aided by extraterrestrially-synthesized molecules. Understanding the origins of life on Earth guides our search for life elsewhere, helping to answer the question of whether biology is unique to Earth. This tutorial review focuses on meteoritic amino acids and nucleobases, exploring modern analytical methods and possible formation mechanisms. We will also discuss the unique window that meteorites provide into the chemistry that preceded life on Earth, a chemical record we do not have access to on Earth due to geologic recycling of rocks and the pervasiveness of biology across the planet. Finally, we will address the future of meteorite research, including asteroid sample return missions.